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Abstract Phosphorus is a key element that plays an essential role in biological processes important for living organisms on Earth. The origin and connection of phosphorus-bearing molecules to early solar system objects and star-forming molecular clouds is therefore of great interest, yet there are limited observations throughout different stages of low-mass (M < a few solar masses) star formation. Observations from the Yebes 40 m and IRAM 30 m telescopes detect for the first time in the 7 mm, 3 mm, and 2 mm bands multiple transitions of PN and PO, as well as a single transition of PO⁺, toward a low-mass starless core. The presence of PN, PO, and PO⁺is kinematically correlated with bright SiO(1–0) emission. Our results reveal not only that shocks are the main driver of releasing phosphorus from dust grains and into the gas phase but that the emission originates from gas not affiliated with the shock itself but quiescent gas that has been shocked in the recent past. From radiative transfer calculations, the PO/PN abundance ratio is found to be $3.1_{-0.6}^{+0.4}$, consistent with other high-mass and low-mass star-forming regions. This first detection of PO⁺toward any low-mass star-forming region reveals a PO⁺/PO ratio of $0.0115_{-0.0009}^{+0.0008}$, a factor of 10 lower than previously determined from observations of a Galactic center molecular cloud, suggesting its formation can occur under more standard Galactic cosmic-ray ionization rates. These results motivate the need for additional observations that can better disentangle the physical mechanisms and chemical drivers of this precursor of prebiotic chemistry. 

ABSTRACT Cold ($$\sim$$10 K) and dense ($$\sim 10^{5}$$ cm$$^{-3}$$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved pre-stellar cores, are the birthplaces of low-mass (M$$\le$$ few M$$_\odot$$) stars. As detections of interstellar complex organic molecules, or COMs, in starless cores has increased, abundance comparisons suggest that some COMs might be seeded early in the star formation process and inherited to later stages (i.e. protostellar discs and eventually comets). To date observations of COMs in starless cores have been limited, with most detections reported solely in the Taurus molecular cloud. It is therefore still a question whether different environments affect abundances. We have surveyed 35 starless and pre-stellar cores in the Perseus molecular cloud with the Arizona Radio Observatory (ARO) 12 m telescope detecting both methanol, CH$$_3$$OH, and acetaldehyde, CH$$_3$$CHO, in 100 per cent and 49 per cent of the sample, respectively. In the sub-sample of 15 cores where CH$$_3$$CHO was detected at $$\gt 3\sigma$$ ($$\sim$$18 mK) with the ARO 12 m, follow-up observations with the Yebes 40 m telescope were carried out. Detections of formic acid, t-HCOOH, ketene, H$$_2$$CCO, methyl cyanide, CH$$_3$$CN, vinyl cyanide, CH$$_2$$CHCN, methyl formate, HCOOCH$$_3$$, and dimethyl ether, CH$$_3$$OCH$$_3$$, are seen in at least 20 per cent of the cores. We discuss detection statistics, calculate column densities, and compare abundances across various stages of low-mass star formation. Our findings have more than doubled COM detection statistics in cold cores and show COMs are prevalent in the gas before star and planet formation in the Perseus molecular cloud. 

Context.Recent JWST observations have measured the ice chemical composition towards two highly extinguished background stars, NIR38 and J110621, in the Chamaeleon I molecular cloud. The observed excess of extinction on the long-wavelength side of the H₂O ice band at 3 μm has been attributed to a mixture of CH₃OH with ammonia hydrates NH₃·H₂O), which suggests that CH₃OH ice in this cloud could have formed in a water-rich environment with little CO depletion. Laboratory experiments and quantum chemical calculations suggest that CH₃OH could form via the grain surface reactions CH₃+ OH and/or C + H₂O in water-rich ices. However, no dedicated chemical modelling has been carried out thus far to test their efficiency. In addition, it remains unexplored how the efficiencies of the proposed mechanisms depend on the astrochemical code employed. Aims.We modelled the ice chemistry in the Chamaeleon I cloud to establish the dominant formation processes of CH₃OH, CO, CO₂, and of the hydrides CH₄and NH₃(in addition to H₂O). By using a set of state-of-the-art astrochemical codes (MAGICKAL, MONACO, Nautilus, UCLCHEM, and KMC simulations), we can test the effects of the different code architectures (rate equation vs. stochastic codes) and of the assumed ice chemistry (diffusive vs. non-diffusive). Methods.We consider a grid of models with different gas densities, dust temperatures, visual extinctions, and cloud-collapse length scales. In addition to the successive hydrogenation of CO, the codes’ chemical networks have been augmented to include the alternative processes for CH₃OH ice formation in water-rich environments (i.e. the reactions CH₃+ OH → CH₃OH and C + H₂O → H₂CO). Results.Our models show that the JWST ice observations are better reproduced for gas densities ≥10⁵cm⁻³and collapse timescales ≥10⁵yr. CH₃OH ice formation occurs predominantly (>99%) via CO hydrogenation. The contribution of reactions CH₃+ OH and C + H₂O is negligible. The CO₂ice may form either via CO + OH or CO + O depending on the code. However, KMC simulations reveal that both mechanisms are efficient despite the low rate of the CO + O surface reaction. CH₄is largely underproduced for all codes except for UCLCHEM, for which a higher amount of atomic C is available during the translucent cloud phase of the models. Large differences in the predicted abundances are found at very low dust temperatures (T_dust<12 K) between diffusive and non-diffusive chemistry codes. This is due to the fact that non-diffusive chemistry takes over diffusive chemistry at such low T_dust. This could explain the rather constant ice chemical composition found in Chamaeleon I and other dense cores despite the different visual extinctions probed. 

Abstract A compact source, G0.02467–0.0727, was detected in Atacama Large Millimeter/submillimeter Array 3 mm observations in continuum and very broad line emission. The continuum emission has a spectral indexα≈ 3.3, suggesting that the emission is from dust. The line emission is detected in several transitions of CS, SO, and SO₂and exhibits a line width FWHM ≈ 160 km s⁻¹. The line profile appears Gaussian. The emission is weakly spatially resolved, coming from an area on the sky ≲1″ in diameter (≲10⁴au at the distance of the Galactic center, GC). The centroid velocity isv_LSR≈ 40–50 km s⁻¹, which is consistent with a location in the GC. With multiple SO lines detected, and assuming local thermodynamic equilibrium (LTE) conditions, the gas temperature isT_LTE= 13 K, which is colder than seen in typical GC clouds, though we cannot rule out low-density, subthermally excited, warmer gas. Despite the high velocity dispersion, no emission is observed from SiO, suggesting that there are no strong (≳10 km s⁻¹) shocks in the molecular gas. There are no detections at other wavelengths, including X-ray, infrared, and radio. We consider several explanations for the millimeter ultra-broad-line object (MUBLO), including protostellar outflow, explosive outflow, a collapsing cloud, an evolved star, a stellar merger, a high-velocity compact cloud, an intermediate-mass black hole, and a background galaxy. Most of these conceptual models are either inconsistent with the data or do not fully explain them. The MUBLO is, at present, an observationally unique object. 

Abstract Prestellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures (<10 K) allow the formation of thick icy dust mantles, which will be partially preserved in future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in prestellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH 3 and, in particular, its deuterated isotopologues appear to maintain high abundances where CO molecules are mainly in the solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH 2 D freeze-out toward the L1544 prestellar core, suggestive of the presence of a “complete depletion zone” within a ≃1800 au radius, in agreement with astrochemical prestellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH 2 D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing out already at ≃7000 au. Radiative transfer effects within the prestellar core cause the NH 2 D(1 11 − 1 01 ) emission to appear centrally concentrated, with a flattened distribution within the central ≃3000 au, unlike the 1.3 mm dust continuum emission, which shows a clear peak within the central ≃1800 au. This prevented NH 2 D freeze-out from being detected in previous observations, where the central 1000 au cannot be spatially resolved.